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[Fizinfo] Szeminárium-Cyril Popov: Deposition, surface modifications, structuring and applications of nano- and ultrananocrystalline films


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  • From: Kugler Szilvia <kugler.szilvia AT wigner.mta.hu>
  • To: fizinfo AT lists.kfki.hu
  • Subject: [Fizinfo] Szeminárium-Cyril Popov: Deposition, surface modifications, structuring and applications of nano- and ultrananocrystalline films
  • Date: Tue, 4 Apr 2017 14:26:13 +0200
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Tisztelt Kollégák!


Szeretném felhívni figyelmüket Cyril Popov előadására, melyre 2017. április 7-én pénteken 10 órától kerül sor az RMI 3. épületének 2. emeleti Tanácstermében.

"Deposition, surface modifications, structuring and applications of nano- and ultrananocrystalline films"

Cyril Popov

/Institute of Nanostructure Technologies and Analytics (INA), Center for Interdisciplinary Nanostructure Science and Technology (CINSaT), University of Kassel, Germany/

popov AT ina.uni-kassel.de

Diamond possesses various unique properties such as extreme hardness, low friction coefficient, chemical inertness, high electrical resistance, excellent thermal conductivity and good biocompatibility. Upon doping it becomes a large band-gap semiconductor with an extremely high breakdown voltage and a high carrier mobility. It is transparent over a wide wavelength range and can withstand high electromagnetic radiation power fluxes from X-ray or laser sources. These outstanding properties make diamond of potential interest for a wide spectrum of applications including wear resistive and transparent protective coatings for optical components, heat spreaders, novel semiconductor devices, etc. However, the diamond coatings prepared by chemical vapor deposition (CVD) techniques are in most cases rough and non-uniform over large areas. The high surface roughness is a major problem for wear resistant applications of diamond films, for example in optical coatings, since it causes attenuation and scattering of the transmitted light. It also hinders the application of polycrystalline diamond films as coatings for bioimplants. A route to overcome the roughness problem is the decrease of the size of the diamond crystallites composing the films, depositing nano- (NCD) and ultrananocrystalline diamond (UNCD) films with grain sizes of several hundred nanometers or up to 10 nm, respectively. We have prepared both types of films by hot filament CVD and microwave plasma CVD and investigated their basic properties, namely morphology, topography, crystallinity, chemical bonding nature. Special attention was paid to the surface properties of NCD and UNCD films and the possibilities for their modifications by plasma or photochemical processes. We have demonstrated the surface modification of NCD films, followed by a functionalization with dye molecules (phthalocyanines) and a thorough characterization of the resulting surfaces by a variety of techniques. The initial photo-electrochemical experiments with such dye-sensitized NCD coatings revealed the generation of photocurrent, which makes them a novel platform for solar energy conversion. We have also investigated the bio-properties of UNCD films, like cytotoxicity, bioinertness, etc., their surface modifications and characterization, and the possibility for their application for long-term growth and investigation of neurons. Applying lithography and plasma etching both types of films can be nanostructured, as demonstrated for example with NCD nanopillars, which can be integrated with color centers.


Minden érdeklődőt szeretettel várunk!

A szervezők nevében üdvözlettel,

Kugler Szilvia

Attachment: Abstract_Popov.doc
Description: MS-Word document



  • [Fizinfo] Szeminárium-Cyril Popov: Deposition, surface modifications, structuring and applications of nano- and ultrananocrystalline films, Kugler Szilvia, 04/04/2017

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